155071
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155071
Aldrich
Azidotrimethylsilane
95%
| Synonym: | Trimethylsilyl azide |
| CAS Number: | 4648-54-8 |
| Linear Formula: | (CH3)3SiN3 |
| Molecular Weight: | 115.21 |
| Beilstein Registry Number: | 1903730 |
| EC Number: | 225-078-5 |
| MDL number: | MFCD00001986 |
| PubChem Substance ID: | 24849336 |
Description
| Packaging | 10, 50 g in glass btl |
| Application | Versatile azidonation reagent for amines,1 amides,2 aldehydes,3 and ketones.3 |
Properties
| assay | 95% |
| refractive index | n |
| bp | 52-53 °C/175 mmHg(lit.) |
| density | 0.868 g/mL at 25 °C(lit.) |
Safety
| Hazard Codes | F,T |
| Risk Statements | 11-23/24/25 |
| Safety Statements | 16-36/37/39-45 |
| RIDADR | UN 1992 3/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 43 °F |
| Flash Point(C) | 6 °C |
References
| Cited Reference | 1. J. Am. Chem. Soc. 115, 9347, (1993) |
| 2. J. Am. Chem. Soc. 116, 4501, (1994) | |
| 3. Synthesis, 106, (1988) | |
| Fieser | Fieser 1,1236 / Fieser 3,316 / Fieser 5,719 / Fieser 6,632 / Fieser 7,394 / Fieser 9,21 / Fieser 10,14 / Fieser 11,32 / Fieser 12,37 / Fieser 13,24 / Fieser 14,25 / Fieser 15,342 / Fieser 16,17 / Fieser 17,23 |
| reference | Aldrich MSDS 1, 141:A / Corp MSDS 1 (1), 326:B / FT-IR 1 (2), 1112:C / FT-IR 2 (3), 4410:D / IR-Spectra (2), 1319:C / IR-Spectra (3), 1542:F / NMR-Reference 2 (2), 1001:B / RegBook 1 (2), 2991:I / Sigma FT-IR 1 (2), 983:B / Structure Index 1, 474:D:1 / Vapor Phase 3, 1651:D |
